jueves, 29 de junio de 2017

Rainer Weiss wins Princess of Asturias Award for Technical and Scientific Research

The 2017 Princess of Asturias Award for Technical and Scientific Research was awarded on June 14 to MIT Professor Emeritus Rainer Weiss and to Caltech physicists Kip S. Thorne and Barry C. Barish and the LIGO Scientific Collaboration.

Weiss was one of the inventors of the laser interferometer gravitational wave detector in the 1970s and co-founded with Thorne and the late Ronald Drever the National Science Foundation Laser Interferometer Gravitational-wave Observatory (LIGO) project in the 1980s to detect gravitational waves. Astronomers had strong indirect evidence for gravitational waves from the measurements of a binary pulsar system between 1970 to 1990. But on Sept. 14, 2015, LIGO made the first direct detection of gravitational waves from the collision of two black holes.

The measurement came from Advanced LIGO, an upgraded version of LIGO’s two large interferometers at Hanford, Washington, and Livingston, Louisiana. Two other detections have been confirmed since then, with the most recent occurring on Jan. 4 of this year. The detections have confirmed Einstein's field equations in the limit of strong gravity and have opened a new field: gravitational wave astronomy.

In addition to receiving the 2017 Princess of Asturias Award for Technical and Scientific Research, Weiss’ contributions to the field for more than 40 years have resulted in numerous awards, including the 2016 Kavli Prize in Astrophysics, a Special Breakthrough Prize in Fundamental Physics, the 2016 Gruber Prize in Cosmology, and the Shaw Prize in Astronomy.

The Princess of Asturias Foundation presents the Asturias Awards for research and discoveries that "contribute to extolling and promoting those scientific, cultural, and humanistic values that form part of the universal heritage of humanity." Weiss and his team were chosen from a field of 39 candidates from 17 different countries. The awards will be presented this autumn in Oviedo, Spain, at a ceremony presided over by Queen Letizia Ortiz Rocasolano and King Felipe VI, the monarchs of Spain. Each awardee will receive a cash prize of 50,000 euros, a diploma, and an insignia. The winners will also receive a sculpture of Joan Miró, one of Spain’s most celebrated artists.



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miércoles, 28 de junio de 2017

Investigating the trap of unemployment

Sitting at a computer screen in a windowless office, a third-year MIT PhD economics student from Paris looks at the latest numbers on France’s unemployment rate. Although the office is located on MIT’s campus, Aicha Ben Dhia’s mind is thousands of miles away. She’s thinking about the people whose lives are reflected in those numbers, and trying to imagine the job search from their point of view.

This summer, Ben Dhia will travel to her home country to conduct field research and meet the people she often envisions while analyzing the data. Working with the French governmental agency Pôle Emploi, she will investigate how workers search for jobs and how employers search for workers. She is dedicated to understanding the practical challenges job seekers face and the consequences of those challenges for the national economy.

The unemployment rate in France is currently around 10 percent. Ben Dhia says that percentage doesn’t include the millions of part-time workers who are still job hunting and are registered with Pôle Emploi.

“It’s even worse for young people between the age of 15 and 24. This group’s unemployment rate is as high as 23 percent,” Ben Dhia says. “Another feature that makes it special in France is long-term unemployment. You have a lot of people in France that have been unemployed for more than a year.”

Tools for the hunt

In France, Ben Dhia says, there is a big push to send job seekers to training programs that can build on existing skills or help them learn new skills. She says it’s easy for economists and government agencies to offer training programs to job seekers and watch the unemployment rate needle bounce up or down. However, there are many other factors that contribute to the success of finding long-lasting employment.

Ben Dhia tries to see the situation from the job seeker’s perspective. Take, for example, a 50-year-old construction worker who has just been laid off.

“Is it better for me to change, to move from one region to another, or is it better for me to start this training program to make me a better construction worker?” she says. “Or is it better that I switch from this sector to a completely different one, like computers?”

Ben Dhia is hoping to discover an efficient way to sort job seekers so they can participate in the most helpful training programs. She is using statistical data and research to inform counselors and job seekers about the best options for securing long-term employment.

During the summer, Ben Dhia will be spending time in France to meet some of these individuals, ask them questions, and better understand the current process of job searching in France. She expects to learn about the underlying obstacles and challenges of an unemployed person in order to better develop strategies to help them find jobs.

Currently, she says, people go about the process in an ad hoc way. Job counselors meet hundreds of job seekers and usually can offer only 30 minutes of their time per person. Furthermore, job applicants may not receive substantial feedback from jobs they are rejected from, which could help them learn from the process. Ben Dhia believes the problems are compounded by job seekers who are paralyzed by their vulnerability. All of this can contribute to the country’s economy on a large scale.

“You have to build yourself,” Ben Dhia says. “And that’s very hard at a time when you’re at your lowest confidence. You doubt yourself very much, but because you have to be pushy and proactive, you have to make decisions to keep going.”

If there was a statistical method based on data that could direct job seekers to the right path, perhaps these challenges could be circumvented, according to Ben Dhia. She hopes to get a better understanding of what job seekers are up against by meeting them in person.

“One of the things I like the most is going to talk to people, a way to sympathize, and work with people,” Ben Dhia says. “I know I’m excited by data, but I think in terms of conceptual problems. Math is cleaner than economics, but I did not do economics to do theory. You want to go concrete and discover how [the problem you’re studying] happens.”

Finding economics

It wasn’t always clear to Ben Dhia that she would eventually study economics. After high school, she spent two years in a preparatory school with a concentration in mathematics and physics. Although her parents are researchers in math and engineering fields, she had always known she wanted to work in social sciences. When she was admitted to a distinguished university in Paris, École Normale Supérieure, which offers courses for a variety of disciplines, Ben Dhia was relieved.

“I was happy I didn’t get accepted into an engineering-only school, because I have two left hands and I’m way more interested in social sciences,” she says.

Her decision to come to MIT and pursue economics sprouted from a manual search through a large book containing alumni contact information. She emailed each alumnus that she thought had interesting background. The first person she met counseled her to challenge herself, try something different, and apply for schools in the U.S.

“Paris, I knew. Math, I knew. I wanted to be challenged with something new, and I wanted something with a social impact that had a math background,” Ben Dhia says.

When she first came to MIT, Ben Dhia was unsure about what area of economics she wanted to pursue. Under the supervision of Esther Duflo, the Abdul Latif Jameel Professor of Poverty Alleviation and Development Economics in the Department of Economics, Ben Dhia traveled to India to implement a project to increase immunization rates of infants in the state of Haryana. Even though the government provided free immunization for children in the state, only 50 percent of infants in Haryana were obtaining basic immunizations by the time they were 1 year old.

While in India, Aicha and her team were trying to scale up an earlier experiment that increased the baseline percentage threefold (from 6 to 18 percent), with a system to keep clinics regularly staffed with nurses and health center workers. After realizing that parents carried their children from distant villages to immunize their child for seemingly inconceivable long-term benefits, the researchers tried compensating visitors with a short-term benefit — a bag of lentils at the end of their visits. This increased the percentage of immunized children from 18 to 36 percent.

“It was fantastic to spend two months in India. Seeing how a project works in practice is very insightful and I learned a lot. More importantly I met incredible people and made great friends” Ben Dhia says.

A love of the outdoors

The year prior to starting graduate school at MIT, Ben Dhia explored other job opportunities. To help a friend, she wrote math lessons for a third-grade textbook that was distributed throughout Senegal. Another friend asked if she could consult on ideas for children’s toys that emphasize the value of trying over success. For half a year Ben Dhia also worked in a private equity investment firm in Senegal. Although she didn’t enjoy the negotiating aspect of the job, Ben Dhia was thankful for the opportunity.

“Working in a different environment, meeting different people, and working in Africa with Africans in a firm that had an exposure to other countries and very high work standards was a short, but very rich experience,” she says.

In Boston, Ben Dhia is physically active, swimming, running, hiking, and especially playing soccer. In France, she says it’s rare for women to play soccer, and as a kid she would play the sport with her brother. Here, whenever and wherever there’s enough grass, she loves to play.

Although Ben Dhia is uncertain about what she will want to do in the future or what kind of career she will have, she thinks a lot about going back to Europe, somewhere new but close to family. It’s clear that Ben Dhia lives for adventures and close relationships with other people.

Economics and statistics can be cold and technical but Ben Dhia’s work is balanced with her loves for travel, playing guitar in the French Alps, a good soccer match on a glossy grass field, her yearly trips to visit family in Tunisia, and the dinners she shares with friends while songs by Salif Keïta, an afro-pop singer-songwriter from Mali, play in the background.

On days when the weather is nice and she still has work to do, Ben Dhia can’t stand her windowless office. She grabs her stuff and searches for a new spot to make a temporary office.

“On sunny days like this, I cannot stay in my office. I look for sun and I look for windows,” she says.



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Kit Cummins awarded the American Chemical Society Pauling Medal

Department of Chemistry Professor Christopher (Kit) Cummins has been honored with the 2017 Linus Pauling Medal, in recognition of his unparalleled synthetic and mechanistic studies of early-transition metal complexes, including reaction discovery and exploratory methods of development to improve nitrogen and phosphorous utilization. Cummins, the Henry Dreyfus Professor of Chemistry, will be presented with the Pauling Medal at an award symposium this fall at Portland State University in Oregon.

"I was introduced to Pauling's hugely influential book 'The Nature of the Chemical Bond' as an undergraduate student at Cornell, where I had the incredible honor to meet Linus when he visited to reprise his Baker lectures from a half century earlier, out of which the book had grown,"  Cummins says. "It is like a dream come true for me to be selected to receive an award named for the human being who gave us so many of chemistry's central concepts. I will dedicate my award lecture to my fantastic students, past and present, for having embarked with me on a rich and still unfolding voyage of scientific discovery."

The Pauling Medal is sponsored jointly by the Portland, Puget Sound, and Oregon sections of the American Chemical Society. It is presented annually in recognition of outstanding achievement in chemistry in the spirit of, and in honor of, Linus Pauling, who was awarded the Nobel Prize in chemistry in 1954 and the Nobel Prize for peace in 1962. Cummins joins several current members of the Department of Chemistry in being named a Linus Pauling Medal awardee, including Tim Swager (2016), Stephen Buchwald (2014), and Stephen Lippard (2009), as well as former department members Alexander Rich (1995) and John Waugh (1984).

Researchers in the Cummins Group are developing new methods of inorganic synthesis to address a variety of interesting questions. The activation of small molecules by transition-metal systems is a featured area, with ongoing work in the areas of synthetic nitrogen fixation, carbon dioxide reduction, and while phosphorus utilization. They are developing thermally activated molecular precursors to reactive small molecules or transient intermediates such as diphosphorus and phosphaethyne, molecules of astrophysical importance. Studies on supramolecular anion receptor host-guest chemistry inform their work on dioxygen electron transfer processes, which are germane to solar energy storage and approaches to improved metal-air battery technology. In addition, Cummins Group researchers work to develop new starting materials in phosphate chemistry including acid forms that provide a starting point for synthesizing new phosphate-based materials with applications in next-generation battery technologies and catalysis. Experimental studies are supplemented with quantum chemical investigations for analysis of chemical bonding, reaction mechanisms, and property predictions.



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Scientists produce dialysis membrane made from graphene

Dialysis, in the most general sense, is the process by which molecules filter out of one solution, by diffusing through a membrane, into a more dilute solution. Outside of hemodialysis, which removes waste from blood, scientists use dialysis to purify drugs, remove residue from chemical solutions, and isolate molecules for medical diagnosis, typically by allowing the materials to pass through a porous membrane.

Today’s commercial dialysis membranes separate molecules slowly, in part due to their makeup: They are relatively thick, and the pores that tunnel through such dense membranes do so in winding paths, making it difficult for target molecules to quickly pass through.

Now MIT engineers have fabricated a functional dialysis membrane from a sheet of graphene — a single layer of carbon atoms, linked end to end in hexagonal configuration like that of chicken wire. The graphene membrane, about the size of a fingernail, is less than 1 nanometer thick. (The thinnest existing memranes are about 20 nanometers thick.) The team’s membrane is able to filter out nanometer-sized molecules from aqueous solutions up to 10 times faster than state-of-the-art membranes, with the graphene itself being up to 100 times faster.

While graphene has largely been explored for applications in electronics, Piran Kidambi, a postdoc in MIT’s Department of Mechanical Engineering, says the team’s findings demonstrate that graphene may improve membrane technology, particularly for lab-scale separation processes and potentially for hemodialysis.

“Because graphene is so thin, diffusion across it will be extremely fast,” Kidambi says. “A molecule doesn’t have to do this tedious job of going through all these tortuous pores in a thick membrane before exiting the other side. Moving graphene into this regime of biological separation is very exciting.”

Kidambi is a lead author of a study reporting the technology, published today in Advanced Materials. Six co-authors are from MIT, including Rohit Karnik, associate professor of mechanical engineering, and Jing Kong, associate professor of electrical engineering.

Plugging graphene

To make the graphene membrane, the researchers first used a common technique called chemical vapor deposition to grow graphene on copper foil. They then carefully etched away the copper and transferred the graphene to a supporting sheet of polycarbonate, studded throughout with pores large enough to let through any molecules that have passed through the graphene. The polycarbonate acts as a scaffold, keeping the ultrathin graphene from curling up on itself.

The researchers looked to turn graphene into a molecularly selective sieve, letting through only molecules of a certain size. To do so, they created tiny pores in the material by exposing the structure to oxygen plasma, a process by which oxygen, pumped into a plasma chamber, can etch away at materials.

“By tuning the oxygen plasma conditions, we can control the density and size of pores we make, in the areas where the graphene is pristine,” Kidambi says. “What happens is, an oxygen radical comes to a carbon atom [in graphene] and rapidly reacts, and they both fly out as carbon dioxide.”

What is left is a tiny hole in the graphene, where a carbon atom once sat. Kidambi and his colleagues found that the longer graphene is exposed to oxygen plasma, the larger and more dense the pores will be. Relatively short exposure times, of about 45 to 60 seconds, generate very small pores.

Desirable defects

The researchers tested multiple graphene membranes with pores of varying sizes and distributions, placing each membrane in the middle of a diffusion chamber. They filled the chamber’s feed side with a solution containing various mixtures of molecules of different sizes, ranging from potassium chloride (0.66 nanometers wide) to vitamin B12 (1 to 1.5 nanometers) and lysozyme (4 nanometers), a protein found in egg white. The other side of the chamber was filled with a dilute solution.

The team then measured the flow of molecules as they diffused through each graphene membrane.

Membranes with very small pores let through potassium chloride but not larger molecules such as L-tryptophan, which measures only 0.2 nanometers wider. Membranes with larger pores let through correspondingly larger molecules.

The team carried out similar experiments with commercial dialysis membranes and found that, in comparison, the graphene membranes performed with higher “permeance,” filtering out the desired molecules up to 10 times faster.

Kidambi points out that the polycarbonate support is etched with pores that only take up 10 percent of its surface area, which limits the amount of desired molecules that ultimately pass through both layers.

“Only 10 percent of the membrane’s area is accessible, but even with that 10 percent, we’re able to do better than state-of-the-art,” Kidambi says.

To make the graphene membrane even better, the team plans to improve the polycarbonate support by etching more pores into the material to increase the membrane’s overall permeance. They are also working to further scale up the dimensions of the membrane, which currently measures 1 square centimeter. Further tuning the oxygen plasma process to create tailored pores will also improve a membrane’s performance — something that Kidambi points out would have vastly different consequences for graphene in electronics applications.

“What’s exciting is, what’s not great for the electronics field is actually perfect in this [membrane dialysis] field,” Kidambi says. “In electronics, you want to minimize defects. Here you want to make defects of the right size. It goes to show the end use of the technology dictates what you want in the technology. That’s the key.”

This research was supported, in part, by the U.S. Department of Energy and a Lindemann Trust Fellowship.



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A new way of extracting copper

MIT researchers have identified the proper temperature and chemical mixture to selectively separate pure copper and other metallic trace elements from sulfur-based minerals using molten electrolysis. This one-step, environmentally friendly process simplifies metal production and eliminates the toxic byproducts such as sulfur dioxide.

Postdoc Sulata K. Sahu and PhD student Brian J. Chmielowiec ’12 decomposed sulfur-rich minerals into pure sulfur and extracted three different metals at very high purity: copper, molybdenum, and rhenium. They also quantified the amount of energy needed to run the extraction process.

An electrolysis cell is a closed circuit, like a battery, but instead of producing electrical energy, it consumes electrical energy to break apart compounds into their elements, for example, splitting water into hydrogen and oxygen. Such electrolytic processes are the primary method of aluminum production and are used as the final step to remove impurities in copper production. Contrary to aluminum, however, there are no direct electrolytic decomposition processes for copper-containing sulfide minerals to produce liquid copper.

The MIT researchers found a promising method of forming liquid copper metal and sulfur gas in their cell from an electrolyte composed of barium sulfide, lanthanum sulfide, and copper sulfide, which yields greater than 99.9 percent pure copper. This purity is equivalent to the best current copper production methods. Their results are published in an Electrochimica Acta paper with senior author Antoine Allanore, assistant professor of metallurgy.

One-step process

“It is a one-step process, directly just decompose the sulfide to copper and sulfur. Other previous methods are multiple steps,” Sahu explains. “By adopting this process, we are aiming to reduce the cost.”

Copper is in increasing demand for use in electric vehicles, solar energy, consumer electronics and other energy efficiency targets. Most current copper extraction processes burn sulfide minerals in air, which produces sulfur dioxide, a harmful air pollutant that has to be captured and reprocessed, but the new method produces elemental sulfur, which can be safely reused, for example, in fertilizers. The researchers also used electrolysis to produce rhenium and molybdenum, which are often found in copper sulfides at very small levels.

The new work builds on a 2016 Journal of The Electrochemical Society paper offering proof of electrolytic extraction of copper authored by Samira Sokhanvaran, Sang-Kwon Lee, Guillaume Lambotte, and Allanore. They showed that addition of barium sulfide to a copper sulfide melt suppressed copper sulfide’s electrical conductivity enough to extract a small amount of pure copper from the high-temperature electrochemical cell operating at 1,105 degrees Celsius (2,021 Fahrenheit). Sokhanvaran is now a research scientist at Natural Resources Canada-Canmet Mining; Lee is a senior researcher at Korea Atomic Energy Research Institute; and Lambotte is now a senior research engineer at Boston Electrometallurgical Corp.

“This paper was the first one to show that you can use a mixture where presumably electronic conductivity dominates conduction, but there is not actually 100 percent. There is a tiny fraction that is ionic, which is good enough to make copper,” Allanore explains.

“The new paper shows that we can go further than that and almost make it fully ionic, that is reduce the share of electronic conductivity and therefore increase the efficiency to make metal,” Allanore says.

These sulfide minerals are compounds where the metal and the sulfur elements share electrons. In their molten state, copper ions are missing one electron, giving them a positive charge, while sulfur ions are carrying two extra electrons, giving them a negative charge. The desired reaction in an electrolysis cell is to form elemental atoms, by adding electrons to metals such as copper, and taking away electrons from sulfur. This happens when extra electrons are introduced to the system by the applied voltage. The metal ions are reacting at the cathode, a negatively charged electrode, where they gain electrons in a process called reduction; meanwhile, the negatively charged sulfur ions are reacting at the anode, a positively charged electrode, where they give up electrons in a process called oxidation.

In a cell that used only copper sulfide, for example, because of its high electronic conductivity, the extra electrons would simply flow through the electrolyte without interacting with the individual ions of copper and sulfur at the electrodes and no separation would occur. The Allanore Group researchers successfully identified other sulfide compounds that, when added to copper sulfide, change the behavior of the melt so that the ions, rather than electrons, become the primary charge carriers through the system and thus enable the desired chemical reactions. Technically speaking, the additives raise the bandgap of the copper sulfide so it is no longer electronically conductive, Chmielowiec explains. The fraction of the electrons engaging in the oxidation and reduction reactions, measured as a percentage of the total current, that is the total electron flow in the cell, is called its faradaic efficiency.

Doubling efficiency

The new work doubles the efficiency for electrolytic extraction of copper reported in the first paper, which was 28 percent with an electrolyte where only barium sulfide added to the copper sulfide, to 59 percent in the second paper with both lanthanum sulfide and barium sulfide added to the copper sulfide.

“Demonstrating that we can perform faradaic reactions in a liquid metal sulfide is novel and can open the door to study many different systems,” Chmielowiec says. “It works for more than just copper. We were able to make rhenium, and we were able to make molybdenum.” Rhenium and molybdenum are industrially important metals finding use in jet airplane engines, for example. The Allanore laboratory also used molten electrolysis to produce zinc, tin and silver, but lead, nickel and other metals are possible, he suggests.

The amount of energy required to run the separation process in an electrolysis cell is proportional to the faradaic efficiency and the cell voltage. For water, which was one of the first compounds to be separated by electrolysis, the minimum cell voltage, or decomposition energy, is 1.23 volts. Sahu and Chmielowiec identified the cell voltages in their cell as 0.06 volts for rhenium sulfide, 0.33 volts for molybdenum sulfide, and 0.45 volts for copper sulfide. “For most of our reactions, we apply 0.5 or 0.6 volts, so that the three sulfides are together reduced to metallic, rhenium, molybdenum and copper,” Sahu explains. At the cell operating temperature and at an applied potential of 0.5 to 0.6 volts, the system prefers to decompose those metals because the energy required to decompose both lanthanum sulfide — about 1.7 volts — and barium sulfide — about 1.9 volts — is comparatively much higher. Separate experiments also proved the ability to selectively reduce rhenium or molybdenum without reducing copper, based on their differing decomposition energies.

Industrial potential

Important strategic and commodity metals including, copper, zinc, lead, rhenium, and molybdenum are typically found in sulfide ores and less commonly in oxide-based ores, as is the case for aluminum. “What’s typically done is you burn those in air to remove the sulfur, but by doing that you make SO2 [sulfur dioxide], and nobody is allowed to release that directly to air, so they have to capture it somehow. There are a lot of capital costs associated with capturing SO2 and converting it to sulfuric acid,” Chmielowiec explains. 

The closest industrial process to the electrolytic copper extraction they hope to see is aluminum production by an electrolytic process known as Hall-Héroult process, which produces a pool of molten aluminum metal that can be continuously tapped. “The ideal is to run a continuous process,” Chmielowiec says. “So, in our case, you would maintain a constant level of liquid copper and then periodically tap that out of the electrolysis cell. A lot of engineering has gone into that for the aluminum industry, so we would hopefully piggyback off of that.”

Sahu and Chmielowiec conducted their experiments at 1,227 C, about 150 degrees Celsius above the melting point of copper. It is the temperature commonly used in industry for copper extraction.

Further improvements

Aluminum electrolysis systems run at 95 percent faradaic efficiency, so there is room for improvement from the researchers’ reported 59 percent efficiency. To improve their cell efficiency, Sahu says, they may need to modify the cell design to recover a larger amount of liquid copper. The electrolyte can also be further tuned, adding sulfides other than barium sulfide and lanthanum sulfide. “There is no one single solution that will let us do that. It will be an optimization to move it up to larger scale,” Chmielowiec says. That work continues.

Sahu, 34, received her PhD in chemistry from the University of Madras, in India. Chmielowiec, 27, a second-year doctoral student and a Salapatas Fellow in materials science and engineering, received his BS in chemical engineering at MIT in 2012 and an MS in chemical engineering from Caltech in 2014.

The work fits into the Allanore Group’s work on high-temperature molten materials, including recent breakthroughs in developing new formulas to predict semiconductivity in molten compounds and demonstrating a molten thermoelectric cell to produce electricity from industrial waste heat. The Allanore Group is seeking a patent on certain aspects of the extraction process.

Novel and significant work

“Using intelligent design of the process chemistry, these researchers have developed a very novel route for producing copper,” says Rohan Akolkar, the F. Alex Nason Associate Professor of Chemical and Biomolecular Engineering at Case Western Reserve University, who was not involved in this work. “The researchers have engineered a process that has many of the key ingredients — it's a cleaner, scalable, and simpler one-step process for producing copper from sulfide ore.”

“Technologically, the authors appreciate the need to make the process more efficient while preserving the intrinsic purity of the copper produced,” says Akolkar, who visited the Allanore lab late last year. “If the technology is developed further and its techno-economics look favorable, then it may provide a potential pathway for simpler and cleaner production of copper metal, which is important to many applications.” Akolkar notes that “the quality of this work is excellent. The Allanore research group at MIT is at the forefront when it comes to advancing molten salt electrolysis research.”

University of Rochester professor ofchemical engineering Jacob Jorné says, “Current extraction processes involve multiple steps and require high capital investment, thus costly improvements are prohibited. Direct electrolysis of the metal sulfide ores is also advantageous as it eliminates the formation of sulfur dioxide, an acid rain pollutant. “

“The electrochemistry and thermodynamics in molten salts are quite different than in aqueous [water-based] systems and the research of Allanore and his group demonstrates that a lot of good chemistry has been ignored in the past due to our slavish devotion to water,” Jorné suggests. “Direct electrolysis of metal ores opens the way to a metallurgical renaissance where new discoveries and processes can be implemented and can modernize the aging extraction industry and improve its energy efficiency. The new approach can be applied to other metals of high strategic importance such as the rare earth metals.”

This work was supported by Norco Conservation and the Office of Naval Research.



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Two MIT documentaries win New England Emmy Awards

On June 24, Boston-area journalists, videographers, and producers filled the halls of the Marriott Boston Copley Place for the 40th annual New England Emmy Awards. Staff from MIT’s Department of Mechanical Engineering (MechE) and MIT Video Productions (MVP) occupied two full tables at the black-tie affair. By the end of the night, two golden statues joined them as both groups were awarded Emmys.

MechE’s multimedia specialist John Freidah was honored with a New England Emmy in the Health/Science Program/Special category for the film “Water is Life,” which chronicles PhD student Natasha Wright and Professor Amos Winter as they travel to India gathering research on how to design a low-cost desalination system for use in developing areas. The film was also recently honored with a 2017 National Edward R. Murrow Award — one of the most prestigious awards in journalism — as well as a 2017 Circle of Excellence Award from the The Council for Advancement and Support of Education (CASE).

Meanwhile, MVP’s Lawrence Gallagher, Joseph McMaster, and Jean Dunoyer received a New England Emmy in the Education/Schools category for their film “A Bold Move,” which recounts MIT’s relocation from Boston’s Back Bay to a swath of undeveloped land on the banks of the Charles River in Cambridge, Massachusetts. The film is the first in a four-part series that commemorate MIT’s 100th year in Cambridge.

"Water Is Life"

As the camera pans over an aerial shot of a lake in India, a flock of white birds majestically flies by. Capturing this moment in the opening shot of “Water is Life” required a lot of patience and a little help from a new friend. Unable to bring a drone into India, the film’s producer, editor, and cinematographer, John Freidah, had to come up with another plan. During a conversation on a flight from Delhi to Hyderabad, Freidah befriended a passenger in his row. He mentioned his search for a drone operator to get the perfect birds-eye-view shot of India’s landscape. As luck would have it, the day before departing India, Freidah received an email from his new friend saying he new someone with a drone that he could use to film sweeping aerial shots.

Planning for “Water is Life” began months before Freidah flew to India, however. Interested in highlighting the important work done in Professor Amos Winter’s Global Engineering and Research (GEAR) Lab, Freidah and his colleagues in the media team at MechE honed in on the research PhD student and Tata Fellow Natasha Wright was conducting on designing an affordable desalination system for use in rural India. With the generous support of Robert Stoner, deputy director of the MIT Energy Initiative and director of the Tata Center for Technology and Design, plans were arranged to film Winter and Wright in India.

“India is a beautiful and amazing country, which is rich in imagery. I felt lucky to film there,” Freidah says. “We were fortunate to have the aid of stakeholders — Jain Engineering and Tata Projects — who facilitated our visits to the local villages where they were struggling with clean drinking water.”

Visiting these villages and talking to end-users who would benefit from and potentially use a desalination system was a crucial component of Winter and Wright’s research. Capturing the daily challenges these villagers face on film brought another level of exposure to the work being done by GEAR and the Tata Center.

“Having John travel to India enabled us to tell the story of our research in much greater depth than we could on campus,” says Winter. By capturing the many angles of Winter and Wright’s story, “Water Is Life” aims to show people first-hand what a problem access to clean water is on a global scale, and how essential it is to support new research and technologies that hope to solve it.

“I really wanted to give the viewer a first-person experience — through the visuals,” Freidah explains. “I wanted it to be a visual journey, as if they were there — with sound and imagery — from honking horns on the street and rickshaws going by.”

"A Bold Move"

It’s hard to imagine a time when the banks of the Charles River in Cambridge weren’t adorned with MIT’s Great Dome, inter-connected buildings, and stately columns. MIT President Richard Cockburn Maclaurin’s aspiration to move the Institute from its overcrowded classrooms in Boston’s Back Bay to a plot of vacant land across the river in 1916 did more than shape the landscape around Kendall Square; it redefined MIT’s presence as a global pioneer in science and technology research. To celebrate the 1916 move to Cambridge, the program A Century in Cambridge was launched last year.

Well before the centennial fireworks exploded over Killian Court, Larry Gallagher, director of MVP, was approached by the Century in Cambridge Steering Committee. MVP was asked to produce a series of documentaries that explored MIT’s move to Cambridge in 1916 and other key aspects of the MIT experience that have helped shape MIT into what it is today. The first of this series, “A Bold Move,” chronicles the design and construction of MIT’s new campus, the whimsical celebrations commemorating the move, and the tragic and untimely passing of the man who orchestrated the entire process — President Maclaurin.

Capturing this period in MIT’s history required extensive research and the participation of faculty, staff, and historians well versed in the move to Cambridge. “We are deeply indebted to the faculty, staff, alumni, and members of the Cambridge community who so generously gave their time end expertise,” says producer and director Joe McMaster. “Without their insights, the film wouldn’t have successfully portrayed this moment in MIT’s history.”

In addition to interviewing those with extensive knowledge of the 2016 move, the MVP team had to dig deep into MIT’s robust archives. Thousands of photos from The MIT Museum, The Institute Archives, the Cambridge Historical Commission, and other sources were analyzed by McMaster and a team of research assistants. “I was amazed to see how thoroughly documented MIT’s history is in photographs — particularly everything to do with the move to Cambridge,” McMaster adds. “The whole affair seemed to be carried out with such a wonderful mixture of seriousness and whimsy, and I hoped the film would capture that feeling.”

Editor and co-producer Jean Dunoyer was tasked with weaving together the footage and photographs in a way that reflected this mixture of the silly and sacred. The imagery and footage was set to period music, to give viewers a feel for that particular era in history. In one of the concluding scenes, this period music is brought to life once more by MIT a capella group The Chorallaries. The group performs a haunting rendition of “Mother Tech,” a piece originally performed at the conclusion of the celebrations in 1916.

The entire Century in Cambridge documentary series was produced over the course of 18 months, with assistance from the Century in Cambridge Steering Committee and the generous support of Jane and Neil Papparlardo '64. The scope of “A Bold Move” required a massive collaboration across all of MVP. “This is indeed a huge collaborative effort for MVP,” says Gallagher. “Projects of this scope benefit from the contributions of the entire team, and for their work and talents to be recognized by their peers in the video production community with an Emmy is a great source of pride.” 



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MIT space hotel wins NASA graduate design competition

An interdisciplinary team of MIT graduate students representing five departments across the Institute was recently honored at NASA's Revolutionary Aerospace Systems Concepts-Academic Linkage Design Competition Forum. The challenge involved designing a commercially enabled habitable module for use in low Earth orbit that would be extensible for future use as a Mars transit vehicle. The team’s design won first place in the competition’s graduate division.

The MIT project — the Managed, Reconfigurable, In-space Nodal Assembly (MARINA) — was designed as a commercially owned and operated space station, featuring a luxury hotel as the primary anchor tenant and NASA as a temporary co-anchor tenant for 10 years. NASA’s estimated recurring costs, $360 million per year, represent an order of magnitude reduction from the current costs of maintaining and operating the International Space Station. Potential savings are approximately 16 percent of NASA’s overall budget — or around $3 billion per year.

MARINA team lead Matthew Moraguez, a graduate student in MIT’s Department of Aeronautics and Astronautics and a member of Professor Olivier L. de Weck’s Strategic Engineering Research Group (SERG), explained that MARINA’s key engineering innovations include extensions to the International Docking System Standard (IDSS) interface; modular architecture of the backbone of MARINA’s node modules; and a distribution of subsystem functions throughout the node modules.

“Modularized service racks connect any point on MARINA to any other point via the extended IDSS interface. This enables companies of all sizes to provide products and services in space to other companies, based on terms determined by the open market,” Moraguez said. “Together these decisions provide scalability, reliability, and efficient technology development benefits to MARINA and NASA.”

MARINA’s design also enables modules to be reused to create an interplanetary Mars transit vehicle that can enter Mars’ orbit, refuel from locally produced methane fuel, and return to Earth.

MARINA and SERG team member George Lordos MBA '00 is currently a graduate fellow in the MIT System Design and Management (SDM) Program, which is offered jointly by the MIT School of Engineering and the MIT Sloan School of Management. Lordos pointed out that MARINA’s engineering design innovations are critical enablers of its commercial viability, which rests on MARINA’s ability to give rise to a value-adding, competitive marketplace in low Earth orbit.

“Just like a yacht marina, MARINA can provide all essential services, including safe harbor, reliable power, clean water and air, and efficient logistics and maintenance,” said Lordos, who will enter the MIT aeronautics and astronautics doctoral program this fall. “This will facilitate design simplicity and savings in construction and operating costs of customer-owned modules. It will also incent customers to lease space inside and outside MARINA’s node modules and make MARINA a self-funded entity that is attractive to investors.”

Valentina Sumini, a postdoc at MIT, contributed to the architectural concept being used for MARINA and its space hotel, along with MARINA faculty advisor Assistant Professor Caitlin Mueller of MIT’s School of Architecture and Planning and Department of Civil and Environmental Engineering.

“MARINA’s flagship anchor tenant, a luxury Earth-facing eight-room space hotel complete with bar, restaurant, and gym, will make orbital space holidays a reality,” said Sumini.

Other revenue-generating features include rental of serviced berths on external International Docking Adapter ports for customer-owned modules and rental of interior modularized rack space to smaller companies that provide contracted services to station occupants. These secondary activities may involve satellite repair, in-space fabrication, food production, and funded research.

Additional members of the MARINA team include: MIT Department of Aeronautics and Astronautics graduate students and SERG members Alejandro Trujillo, Samuel Wald, and Johannes Norheim; MIT Department of Civil and Environmental Engineering undergraduate Zoe Lallas; MIT School of Architecture and Planning graduate students Alpha Arsano and Anran Li; and MIT Integrated Design and Management Program graduate students Meghan Maupin and John Stillman.



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